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仪器网/ 行业应用/ 解决方案/ A Europium Complex With Excellent Two-Photon-Sensiti

A Europium Complex With Excellent Two-Photon-Sensiti

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We report the synthesis and excellent two-photon-sensitized luminescence properties of a new complex [Eu(tta)3dmbpt] (tta =
henoyltrifluoroacetonate; dmbpt = 2-(N,N-diethyl-2,6-dimethylanilin-4-yl)-4,6-bis(3,5-dimethylpyrazol-1-yl)-1,3,5-triazine) that
exhibits the highest efficiency of lanthanide luminescence when excited by near-infrared (NIR) laser pulses (action cross section
of two-photon-excited fluorescence d ×UF: 85 GM at 812 nm and 56 GM at 842 nm; 1 GM= 1050 cm4 s photon1 molecule
1). Compared to a previously reported [Eu(tta)3dpbt] complex, (dpbt = 2-(N,N-diethylanilin-4-yl)-4,6-bis(3,5-dimethylpyrazol-
1-yl)-1,3,5-triazine), [Eu(tta)3dmbpt] has two excess methyl groups at the 2,6-positions of the phenyl ring. Crystallographic
data of dmbpt show that the 2,6-dimethyl substitutes bring about a significant twist in the conformation of the diethylamino
group compared to that in dpbt, which severely influences the conjugation in the ground state between the electron lone pair of
N in the N(CH2)2 moiety and the aromatic electron system in dmbpt. The large two-photon absorption (TPA) cross section
of dmbpt is mainly derived from its large static dipole moment difference between the S0 and the S1 states, which is partly
responsible for the high capability of two-photon-sensitized luminescence of [Eu(tta)3dmbpt]. The broader two- and
single-photon excitation windows and the superior two-photon-sensitized luminescent properties in the long-wavelength NIR
region of [Eu(tta)3dmbpt] compared to [Eu(tta)3dpbt] are also explained according to the calculated results and twisted
structure.
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